I have just changed my key setting so that I can leave teamspeak on voice detect, which means that anything I say will go over teamspeak, but I have changed it so that the ingame chat key will turn off the mic in teamspeak while I am talking ingame.
To do that, set your teamspeak to Voice Activation Detection, and set the level so that it does not activate on background noise.
Then go to hotkeys:
(I use z for ingame chat)
and set it to this:
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